FIGURE 2.18. Torsion angles that define the conformation of the glycosidic linkages φ, ψ, and ω.

FIGURE 2.18

Torsion angles that define the conformation of the glycosidic linkages φ, ψ, and ω. (a) Newman projection along the C1—O1 bond illustrating φ for the 1∅︀ 6 glycosidic bond. (b) Newman projection along the C6′—O1 bond illustrating ψ for a 1∅︀6 linkage. (c) Newman projection along the C5′—C6′ bond illustrating ω for a 1∅︀6 linkage. The lobes on the glycosidic oxygen atom represent lone pairs of electrons. The torsion angles depicted are arbitrary and do not necessarily reflect the most stable conformation.

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From: Chapter 2, Structural Basis of Glycan Diversity

Cover of Essentials of Glycobiology
Essentials of Glycobiology. 2nd edition.
Varki A, Cummings RD, Esko JD, et al., editors.
Cold Spring Harbor (NY): Cold Spring Harbor Laboratory Press; 2009.
Copyright © 2009, The Consortium of Glycobiology Editors, La Jolla, California.

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