Abstract
A Rh(III)-catalyzed protocol for the amidation of anilide and enamide C-H bonds with isocyanates has been developed. This method provides direct and efficient syntheses of N-acyl anthranilamides, enamine amides, and pyrimidin-4-one heterocycles.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Amides / chemical synthesis*
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Amides / chemistry
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Catalysis
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Isocyanates / chemistry*
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Molecular Structure
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Organometallic Compounds / chemistry*
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Rhodium / chemistry*
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Stereoisomerism
Substances
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Amides
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Isocyanates
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Organometallic Compounds
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Rhodium