Abstract
The first rhodium-catalyzed arylation of imines proceeding via C-H bond functionalization is reported. Use of a non-coordinating halide abstractor is important to obtain reactivity. Aryl-branched N-Boc-amines are formed, and a wide range of functionality is compatible with the reaction.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Carbon / chemistry*
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Catalysis
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Formic Acid Esters / chemistry*
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Hydrogen / chemistry*
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Imines / chemistry*
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Pyridines / chemistry
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Rhodium / chemistry*
Substances
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Formic Acid Esters
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Imines
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Pyridines
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t-butyloxycarbonyl group
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Carbon
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Hydrogen
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Rhodium
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pyridine