In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp C-H Bond

Siddhartha Das; Gary W Brudvig; Robert H Crabtree

doi:10.1016/j.ica.2008.06.009

In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp C-H Bond

Inorganica Chim Acta. 2009 Mar 2;362(4):1229-1233. doi: 10.1016/j.ica.2008.06.009.

Authors

Siddhartha Das¹, Gary W Brudvig, Robert H Crabtree

Affiliation

¹ Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut, 06520-8107.

Abstract

We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O(2)-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.

Abstract

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