Abstract
A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Catalysis
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Crystallography, X-Ray
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Iridium / chemistry*
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Ligands
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Methane / analogs & derivatives
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Methane / chemical synthesis
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Methane / chemistry
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Models, Molecular
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Molecular Structure
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Oxidation-Reduction
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Pyridines / chemical synthesis
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Pyridines / chemistry*
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Thermodynamics
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Water / chemistry*
Substances
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Ligands
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Pyridines
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Water
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methyl radical
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Iridium
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pyridine
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Methane