Carboxylate-rich hybrid ligands in Mn(II) complexes as precursors for water oxidation reactions

C R Raymond Gan; Zhaolin Liu; Shi-Qiang Bai; Kian Soo Ong; T S Andy Hor

doi:10.1039/c3dt51666k

Carboxylate-rich hybrid ligands in Mn(II) complexes as precursors for water oxidation reactions

Dalton Trans. 2014 Jan 28;43(4):1821-8. doi: 10.1039/c3dt51666k.

Authors

C R Raymond Gan¹, Zhaolin Liu, Shi-Qiang Bai, Kian Soo Ong, T S Andy Hor

Affiliation

¹ NUS Graduate School for Integrative Sciences and Engineering, Center for Life Sciences, #05-01, 28 Medical Drive Singapore 117456, Singapore.

PMID: 24253856
DOI: 10.1039/c3dt51666k

Abstract

A new family of Mn(II) complexes stabilized by carboxylate-rich hybrid ligands has been synthesized, characterized and applied as catalytic precursors for MnO2 nanoparticles in water oxidation by (NH4)2Ce(NO3)6.