Abstract
A novel dicyanoosmium(III) complex, trans-Ph(4)P[Os(III)(salen)(CN)(2)].CH(2)Cl(2).H(2)O (1; Ph(4)P(+) = tetraphenylphosphonium cation, salen(2-) = N,N'-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me(3)tacn)(H(2)O)(2)](ClO(4))(2) (Me(3)tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)(2)](2)[Cu(Me(3)tacn)].CH(3)OH (2) and [Os(salen)(CN)(2)][Cu(Me(3)tacn)].ClO(4) (3).
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aza Compounds / chemistry*
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Catalysis
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Crystallography, X-Ray
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Drug Design
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Ethylenediamines / chemistry*
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Ferric Compounds / chemistry
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Heterocyclic Compounds / chemistry*
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Hydrogen Peroxide / chemistry
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Kinetics
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Magnetics / methods
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Models, Chemical
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Molecular Structure
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Piperidines / chemistry*
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Spectroscopy, Fourier Transform Infrared / methods
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Thermodynamics
Substances
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1,4,7-trimethyl-1,4,7-triazacyclononane
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Aza Compounds
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Ethylenediamines
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Ferric Compounds
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Heterocyclic Compounds
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Piperidines
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triazacyclononane
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ferrite
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1,4,7-triazacyclononane
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disalicylaldehyde ethylenediamine
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Hydrogen Peroxide