Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO(2)Et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reactions

Chemistry. 2009 Oct 19;15(41):10707-12. doi: 10.1002/chem.200901895.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Methane / analogs & derivatives*
  • Methane / chemistry
  • Molecular Conformation
  • Molecular Structure
  • Porphyrins / chemical synthesis*
  • Porphyrins / chemistry
  • Ruthenium / chemistry*
  • Stereoisomerism

Substances

  • Porphyrins
  • carbene
  • Ruthenium
  • Methane