Abstract
Reaction of a pinene-based pyridylthioamide with 1,4-dibromo-2,3-butanedione in refluxing methanol yielded a new chiral pyridylthiazole ligand L which forms a dinuclear double-stranded helicate with Cu(i) ions; this helicate has opposite helical chirality when compared with its quaterpyridine analogue.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Butanones / chemical synthesis
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Cations, Divalent / chemistry
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Copper / chemistry*
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Ligands
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Stereoisomerism
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Thiazoles / chemical synthesis*
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Thiazoles / chemistry
Substances
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Butanones
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Cations, Divalent
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Ligands
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Thiazoles
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1,4-dibromobutanedione
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Copper