Aryl C-glycosylation of phenols with glycosyl trifluoroacetimidates

Yuwen Li; Guo Wei; Biao Yu

doi:10.1016/j.carres.2006.08.022

Aryl C-glycosylation of phenols with glycosyl trifluoroacetimidates

Carbohydr Res. 2006 Nov 27;341(16):2717-22. doi: 10.1016/j.carres.2006.08.022. Epub 2006 Sep 15.

Authors

Yuwen Li¹, Guo Wei, Biao Yu

Affiliation

¹ State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China.

PMID: 16978594
DOI: 10.1016/j.carres.2006.08.022

Abstract

Aryl C-glycosylation of a variety of phenols with glycosyl trifluoroacetimidates in the presence of TMSOTf was examined, leading to the corresponding ortho-hydroxyaryl C-glycosides in variable yields.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Acetamides
Fluoroacetates
Glycosylation
Mesylates / chemistry
Phenols / chemistry*
Trifluoroacetic Acid / chemistry
Trimethylsilyl Compounds

Substances

Acetamides
Fluoroacetates
Mesylates
Phenols
Trimethylsilyl Compounds
trimethylsilyl trifluoromethanesulfonate
trifluoroacetamide
Trifluoroacetic Acid