Abstract
Treatment of [Ru(II)(Por)(CO)] [Por = porphyrinato(2-)] and O=PCl(2)R [R = Ad (adamantyl), Bu(t), Bu(sec)] or PCl2Mes (Mes = mesityl) with LiAlH4 afforded primary alkyl- and arylphosphine complexes [Ru(II)(Por)(PH2R)2], which have been isolated in pure form and characterized by 1H NMR, 31P NMR, IR, and UV-vis spectroscopy and mass spectrometry. The structures of [Ru(II)(TTP)(PH2Ad)2] and [Ru(II)(F20-TPP)(PH2Mes)2] were determined by X-ray crystallography.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Chlorine / chemistry
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Crystallization
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Crystallography, X-Ray
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Ligands
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Magnetic Resonance Spectroscopy
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Mass Spectrometry
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Metalloporphyrins / chemistry*
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Metals / chemistry
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Models, Chemical
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Models, Molecular
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Oxygen / chemistry*
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Phosphines / chemical synthesis*
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Phosphines / chemistry
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Protons
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Spectrophotometry, Infrared / methods
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Spectrophotometry, Ultraviolet
Substances
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Ligands
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Metalloporphyrins
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Metals
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Phosphines
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Protons
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Chlorine
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Oxygen