When electron exchange is chemical exchange-assignment of 1H NMR spectra of paramagnetic cobalt(II)-2,2':6'2''-terpyridine complexes

Hoi Shan Chow; Edwin C Constable; Catherine E Housecroft; Klaus J Kulicke; Yaqiu Tao

doi:10.1039/b415419c

When electron exchange is chemical exchange-assignment of 1H NMR spectra of paramagnetic cobalt(II)-2,2':6'2''-terpyridine complexes

Dalton Trans. 2005 Jan 21:(2):236-7. doi: 10.1039/b415419c. Epub 2004 Dec 10.

Authors

Hoi Shan Chow¹, Edwin C Constable, Catherine E Housecroft, Klaus J Kulicke, Yaqiu Tao

Affiliation

¹ Department of Chemistry, University of Basel, Spitalstrasse 51, CH 4056, Basel, Switzerland.

PMID: 15616710
DOI: 10.1039/b415419c

Abstract

Electron exchange between [Co(terpy)2]3+ and [Co(terpy)2]2+ can be monitored by 1H NMR exchange spectroscopy and allows the cobalt(II) spectra to be fully assigned.