Abstract
Reaction of mono- and dinuclear gold(I) phosphine chloride precursors with an excess of organolithium reagent C14H9Li in dry diethyl ether or THF gave mononuclear [(PPh3)Au(C9H14)] and dinuclear [(P--P)Au2(C14H9)2] (P--P = dppm, dcpm) and [(dcpm)Au2Br(C14H9)], respectively. These complexes were found to be emissive both in the solid state and in fluid solutions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Anthracenes / chemistry
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Crystallography, X-Ray
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Electrochemistry
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Gold / chemistry*
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Luminescent Measurements*
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Models, Chemical
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Models, Molecular
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Molecular Structure
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Organometallic Compounds* / chemical synthesis
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Organometallic Compounds* / chemistry
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Photochemistry
Substances
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Anthracenes
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Organometallic Compounds
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Gold
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anthracene