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Select item 85878001.

Experimental and Theoretical DFT Investigations in the [2,3]-Wittig-Type Rearrangement of Propargyl/Allyl-Oxy-Pyrazolones

Lucia De Crescentini, Gianfranco Favi, Giacomo Mari, Gianluca Ciancaleoni, Marcello Costamagna, Stefania Santeusanio, Fabio Mantellini

Molecules. 2021 Nov; 26(21): 6557. Published online 2021 Oct 29. doi: 10.3390/molecules26216557

PMCID:: PMC8587800

Abstract Article PDF–3.3M

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Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications

Oscar Pàmies, Jèssica Margalef, Santiago Cañellas, Jinju James, Eric Judge, Patrick J. Guiry, Christina Moberg, Jan-E. Bäckvall, Andreas Pfaltz, Miquel A. Pericàs, Montserrat Diéguez

Chem Rev. 2021 Apr 28; 121(8): 4373–4505. Published online 2021 Mar 19. doi: 10.1021/acs.chemrev.0c00736

PMCID:: PMC8576828

Abstract Article PDF–32M

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From Natural Sources to Synthetic Derivatives: The Allyl Motif as a Powerful Tool for Fragment-Based Design in Cancer Treatment

Nora Astrain-Redin, Carmen Sanmartin, Arun K. Sharma, Daniel Plano

J Med Chem. 2023 Mar 23; 66(6): 3703–3731. Published online 2023 Mar 1. doi: 10.1021/acs.jmedchem.2c01406

PMCID:: PMC10041541

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Allyl Cyanate/Isocyanate Rearrangement in Glycals: Stereoselective Synthesis of 1-Amino and Diamino Sugar Derivatives

Stefania Mirabella, Giulia Petrucci, Cristina Faggi, Camilla Matassini, Francesca Cardona, Andrea Goti

Org Lett. 2020 Nov 20; 22(22): 9041–9046. Published online 2020 Nov 4. doi: 10.1021/acs.orglett.0c03438

PMCID:: PMC7735751

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Switching Selectivity in Borylative Allyl–Allyl Cross-Coupling through Synergistic Catalysis

Nuria Vázquez-Galiñanes, Giuseppe Sciortino, Martín Piñeiro-Suárez, Balázs L. Tóth, Feliu Maseras, Martín Fañanás-Mastral

J Am Chem Soc. 2024 Aug 7; 146(31): 21977–21988. Published online 2024 Jul 24. doi: 10.1021/jacs.4c07188

PMCID:: PMC11311230

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Difluorocarbene-induced [1,2]- and [2,3]-Stevens rearrangement of tertiary amines

Jianke Su, Yu Guo, Chengbo Li, Qiuling Song

Nat Commun. 2024; 15: 4794. Published online 2024 Jun 5. doi: 10.1038/s41467-024-49054-x

PMCID:: PMC11153565

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Glucosinolate structural diversity shapes recruitment of a metabolic network of leaf-associated bacteria

Kerstin Unger, Syed Ali Komail Raza, Teresa Mayer, Michael Reichelt, Johannes Stuttmann, Annika Hielscher, Ute Wittstock, Jonathan Gershenzon, Matthew T. Agler

Nat Commun. 2024; 15: 8496. Published online 2024 Oct 1. doi: 10.1038/s41467-024-52679-7

PMCID:: PMC11445407

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Allyl nitrile: Toxicity and health effects

Hideji Tanii

J Occup Health. 2017 Mar 20; 59(2): 104–111. Published online 2017 Jan 28. doi: 10.1539/joh.16-0147-RA

PMCID:: PMC5478528

Abstract Article PDF–117K

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Recent advances in metal-catalysed asymmetric sigmatropic rearrangements

Yangbin Liu, Xiaohua Liu, Xiaoming Feng

Chem Sci. 2022 Nov 2; 13(42): 12290–12308. Published online 2022 Sep 23. doi: 10.1039/d2sc03806d

PMCID:: PMC9629009

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Unexpected Rearrangement of N-Allyl-2-phenyl-4,5-Dihydrooxazole-4-Carboxamides to Construct Aza-Quaternary Carbon Centers

Goyeong Choi, Seoyoung Jo, Juyeon Mun, Yonguk Jeong, Seok-Ho Kim, Jong-Wha Jung

Molecules. 2019 Dec; 24(24): 4495. Published online 2019 Dec 8. doi: 10.3390/molecules24244495

PMCID:: PMC6943665

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Assessing Bioavailability and Bioactivity of 4-Hydroxythiazolidine-2-Thiones, Newly Discovered Glucosinolate Degradation Products Formed During Domestic Boiling of Cabbage

Holger Hoffmann, Christiane Ott, Jana Raupbach, Lars Andernach, Matthias Renz, Tilman Grune, Franziska S. Hanschen

Front Nutr. 2022; 9: 941286. Published online 2022 Jul 22. doi: 10.3389/fnut.2022.941286

PMCID:: PMC9354954

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Aromatic Cope Rearrangements

Breanna M. Tomiczek, Alexander J. Grenning

Org Biomol Chem. Author manuscript; available in PMC 2022 May 18.

Published in final edited form as: Org Biomol Chem. 2021 Mar 21; 19(11): 2385–2398. Published online 2021 Mar 2. doi: 10.1039/d1ob00094b

PMCID:: PMC9115579

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Coordination of Glucosinolate Biosynthesis and Turnover Under Different Nutrient Conditions

Verena Jeschke, Konrad Weber, Selina Sterup Moore, Meike Burow

Front Plant Sci. 2019; 10: 1560. Published online 2019 Dec 6. doi: 10.3389/fpls.2019.01560

PMCID:: PMC6909823

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Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids

Tyler J. Fulton, Alexander Q. Cusumano, Eric J. Alexy, Yun E. Du, Haiming Zhang, K. N. Houk, Brian M. Stoltz

J Am Chem Soc. Author manuscript; available in PMC 2021 Dec 30.

Published in final edited form as: J Am Chem Soc. 2020 Dec 30; 142(52): 21938–21947. Published online 2020 Dec 15. doi: 10.1021/jacs.0c11480

PMCID:: PMC8552564

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Nitrile Oxide, Alkenes, Dipolar Cycloaddition, Isomerization and Metathesis Involved in the Syntheses of 2-Isoxazolines

Stanisław Krompiec, Piotr Lodowski, Aneta Kurpanik-Wójcik, Bogumiła Gołek, Angelika Mieszczanin, Aleksandra Fijołek, Marek Matussek, Klaudia Kaszuba

Molecules. 2023 Mar; 28(6): 2547. Published online 2023 Mar 10. doi: 10.3390/molecules28062547

PMCID:: PMC10051332

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Base-Mediated Claisen Rearrangement of CF₃-Containing Bisallyl Ethers

Yoko Hamada, Rio Matsunaga, Tomoko Kawasaki-Takasuka, Takashi Yamazaki

Molecules. 2021 Jul; 26(14): 4365. Published online 2021 Jul 19. doi: 10.3390/molecules26144365

PMCID:: PMC8304132

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Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones

Haifeng Zheng, Yan Wang, Chaoran Xu, Xi Xu, Lili Lin, Xiaohua Liu, Xiaoming Feng

Nat Commun. 2018; 9: 1968. Published online 2018 May 17. doi: 10.1038/s41467-018-04123-w

PMCID:: PMC5958103

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Chiral cobalt(ii) complex-promoted asymmetric para-Claisen rearrangement of allyl α-naphthol ethers

Hongkun Zeng, Lifeng Wang, Zhishan Su, Meijia Ying, Lili Lin, Xiaoming Feng

Chem Sci. 2023 Dec 6; 14(47): 13979–13985. Published online 2023 Nov 27. doi: 10.1039/d3sc05677e

PMCID:: PMC10699576

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Select item 653079219.

Allylic azides: synthesis, reactivity, and the Winstein rearrangement

Angela S. Carlson, Joseph J. Topczewski

Org Biomol Chem. Author manuscript; available in PMC 2020 May 8.

Published in final edited form as: Org Biomol Chem. 2019 May 8; 17(18): 4406–4429. doi: 10.1039/c8ob03178a

PMCID:: PMC6530792

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Select item 949080520.

Catalytic Enantioselective Synthesis of α-Difunctionalized Cyclic Sulfones

Eleanor Bowen, Gillian Laidlaw, Bethany C. Atkinson, Timur A. McArdle-Ismaguilov, Vilius Franckevičius

J Org Chem. 2022 Aug 5; 87(15): 10256–10276. Published online 2022 Jul 8. doi: 10.1021/acs.joc.2c01240

PMCID:: PMC9490805

Abstract Article PDF–3.0M

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Scheme 5Iterative Allyl Cyanate/Isocyanate Rearrangement to Yield the 1,2-Diamino Sugar 27

Allyl Cyanate/Isocyanate Rearrangement in Glycals: Stereoselective Synthesis of 1-Amino and Diamino Sugar Derivatives

Org Lett. 2020 Nov 20;22(22):9041-9046.
Fig. 2DFT calculations on rearrangement pathways and proposed asymmetric induction models for both aryl and alkyl allyl ethers.

Chiral cobalt(ii) complex-promoted asymmetric para-Claisen rearrangement of allyl α-naphthol ethers

Chem Sci. 2023 Dec 6;14(47):13979-13985.
Scheme 1Known Procedures for the Synthesis of N-Glycosides from Glycals and the Strategy Reported Herein Based on the Allyl Cyanate/Isocyanate Rearrangement

Allyl Cyanate/Isocyanate Rearrangement in Glycals: Stereoselective Synthesis of 1-Amino and Diamino Sugar Derivatives

Org Lett. 2020 Nov 20;22(22):9041-9046.
Scheme 1

Ireland–Claisen rearrangement of allyl esters 1a–c.

Why do thioureas and squaramides slow down the Ireland–Claisen rearrangement?

Beilstein J Org Chem. 2019;15:2948-2957.

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allyl rearrangement (4602)
PMC
ubiquitin family protein [Arabidopsis lyrata subsp. lyrata]
ubiquitin family protein [Arabidopsis lyrata subsp. lyrata]
gi|297325088|gb|EFH55508.1||gnl|WGS |ARALYDRAFT_901986

Protein
Listeria monocytogenes strain 2964 contig_30, whole genome shotgun sequence
Listeria monocytogenes strain 2964 contig_30, whole genome shotgun sequence
gi|1034746449|gb|LXQU01000030.1||gn :LXQU01|contig_30

Nucleotide
Lacticaseibacillus casei strain PB2021-BA03 contig00151, whole genome shotgun se...
Lacticaseibacillus casei strain PB2021-BA03 contig00151, whole genome shotgun sequence
gi|2229922152|ref|NZ_JAGEVI01000015 gnl|WGS:NZ_JAGEVI01|contig00151

Nucleotide
Mycobacterium sp. UM_Kg27 contig000061, whole genome shotgun sequence
Mycobacterium sp. UM_Kg27 contig000061, whole genome shotgun sequence
gi|807963208|gb|JRMM01000061.1||gnl JRMM01|contig000061

Nucleotide

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